Evaluation of the use of photochemical indicators to assess ozone—NOx—VOC sensitivity in the Southwestern Iberian Peninsula     

Nuria Castell  Ariel F. Stein  Enrique Mantilla  Rosa Salvador  Millán Millán 《Journal of Atmospheric Chemistry》2009,63(1):73-91

Understanding the chemical links between ozone (O₃) and its two main precursors, nitrogen oxides (NOx) and volatile organic compounds (VOC), is important for designing effective photochemical smog reduction strategies. This chemical relationship will determine which precursor (NOx or VOC) emission reduction will be more effective for decreasing the ozone formation. Under certain conditions, ozone levels decrease as a result of a reduction in NOx emissions but do not respond significantly to changes in VOC emissions (NOx-sensitive condition), while under other conditions ozone concentrations decrease in response to reductions in VOCs and may even increase when NOx emissions are reduced (VOC-sensitive conditions). Indicator species can be used to assess the sensitivity of ozone to changes in the emissions of its precursors. These indicators are species or species ratios involved in ozone photochemistry which reflect the primary chemical process through which the ozone was formed. In this work we use the MM5-CAMx model system to explore the behaviour of various indicator species during two meteorological situations featuring different atmospheric conditions in a complex terrain area. The results show that indicators based on nitrogen compounds (i.e,. NOy and NOz) are suitable for defining the transition range from VOC- to NOx-sensitive chemistry, and that despite the uncertainties associated with the use of chemical indicators, the ratios O₃/NOy and O₃/NOz may provide a simple and useful way to summarize the response of ozone to changes in NOx and VOC emissions in Southwestern Spain.  相似文献   

A spring and wooded habitat at FLK Zinj and their relevance to origins of human behavior     

Gail M. Ashley  Doris Barboni  Manuel Dominguez-Rodrigo  Henry T. Bunn  Audax Z.P. Mabulla  Fernando Diez-Martin  Rebeca Barba  Enrique Baquedano 《Quaternary Research》2010,74(3):304-314

The 1959 discovery of the hominin fossil Zinjanthropus boisei brought the world's attention to the rich records at Olduvai Gorge, Tanzania. Subsequent excavations of archaeological level 22 (FLK Zinj) Bed I uncovered remains of Homo habilis and a high-density collection of fossils and Oldowan stone tools. The occurrence of this unusual collection of bones and tools at this specific location has been controversial for decades. We present paleoecological data that provide new insights into the origin of FLK Zinj. Our recent excavations 200 m north of the site uncovered a 0.5-m-thick tufa mound draped by Tuff IC, in the same stratigraphic horizon as level 22. Stable isotope analyses indicate that the carbonates were deposited by a freshwater spring. Phytolith analysis of the waxy clay under Tuff IC revealed abundant woody dicotyledon and palm phytoliths, indicating that the site was wooded to densely wooded. The time equivalency and close physical proximity of the two environments indicate the two are related. This study has provided the first documented evidence of springs in Bed I and these data have important implications for the interpretation of hominin behavior in meat acquisition and the ongoing debate on scavenging versus hunting.  相似文献   

Mesozoic Evaniidae (Insecta: Hymenoptera) in Spanish Amber: Reanalysis of the Phylogeny of the Evanioidea     

Enrique PE?ALVER  Jaime ORTEGA-BLANCO  André NEL  Xavier DELCLòS 《《地质学报》英文版》2010,84(4):809-827

<正>One new genus and five new species of the family Evaniidae are described from the Early Cretaceous (Albian)Spanish amber of Penacerrada-Ⅰ(Province of Burgos),San Just and Arroyo de la Pascueta(both in the Province of Teruel):Cretevania alonsoi sp.nov.,C.montoyai sp.nov.,C.alcalai sp.nov.,C.rubusensis sp.nov.,and Iberoevania roblesi gen.and sp.nov.Taxonomic changes include Cretevania pristina(Zhang and Zhang,2000) comb.nov.,C.exquisita(Zhang,Rasmtsyn,Wang and Zhang,2007)comb.nov.,C.vesca(Zhang,Rasnitsyn,Wang and Zhang,2007)comb.nov.,and C.cyrtocerca(Deans,2004)comb.nov.,as a result of the reinterpretation of the genera Procretevania and Eovernevania.The new well preserved specimens of the genus Cretevania,together with the characters shown by the type specimens of the synonymized genera,give new information about their anatomical characters of taxonomical importance,and the genus Cretevania Rasnitsyn,1975 is re-diagnosed.The holotypes of the Russian species in amber have been revised.A cladistic analysis of fossil and extant groups of the superfamily Evanioidea is included.Cretevania had a wide palaeogeographic distribution,with the highest diversity known from Spain.The 13 known Cretevania species show a high interspecific variation mainly in wing characteristics,and a wide range of body and wing size.  相似文献   

The white dwarf luminosity function – II. The effect of the measurement errors and other biases     

Santiago Torres  Enrique García-Berro  Jordi Isern 《Monthly notices of the Royal Astronomical Society》2007,378(4):1461-1470

The disc white dwarf luminosity function is an important tool for studying the solar neighbourhood, since it allows the determination of several Galactic parameters, the most important one being the age of the Galactic disc. However, only the     method has been employed so far for observationally determining the white dwarf luminosity function, whereas for other kind of luminosity functions several other methods have been frequently used. Moreover, the procedures to determine the white dwarf luminosity function are not free of biases. These biases have two different origins: they can either be of statistical nature or a consequence of the measurement errors. In a previous paper we carried out an in-depth study of the first category of biases for several luminosity function estimators. In this paper we focus on the biases introduced by the measurement errors and on the effects of the degree of contamination of the input sample used to build the disc white dwarf luminosity function by different kinematical populations. To assess the extent of these biases we use a Monte Carlo simulator to generate a controlled synthetic population and analyse the behaviour of the disc white dwarf luminosity function for several assumptions about the magnitude of the measurement errors and for several degrees of contamination, comparing the performances of the most robust luminosity function estimators under such conditions.  相似文献   

Late Pleistocene (Last Interglacial) terrace deposits, Bahia Coyote, Baja California Sur, México     

Teresa DeDiego- Forbis  Robert Douglas  Donn Gorsline  Enrique Nava-Sanchez  Larry Mack  Jay Banner 《Quaternary International》2004,120(1):29

Late Pleistocene age terrace deposits are exposed in the narrow cliffed coastal plain of Bahia Coyote, Baja California Sur, resting unconformably on the lagoonal-shallow water volcaniclastics of the early Miocene Cerro Colorado Member of the El Cien Formation. The terrace is dissected by widely spaced arroyos and partically covered by alluvial fans in the inner and central areas. The marine deposits vary in thickness from 0.5 to 10 m and were laid down in pre-existing erosional channels and depressions in the Pleistocene landscape. The sequence begins with a cobble conglomerate with oyster shells, overlain by poorly bedded molluscan-rich bioclastic sands and coral rubble, beds of massive Porites in growth position and coral-rhodolith sands and marls. Beach sands and gravels and coastal dunes cap the sequence.Samples of Porites panamensis selected for U/Th dating are well-preserved aragonite (>95%). Preliminary results yield U/Th ages of 109–209 ka but the corals have initial δ ²³⁴U values in excess of modern seawater values. This indicates open-system behavior and uncertainty associated with the ages. A corrected age for the top of the massive Porites unit suggests that the corals grew during the last interglacial, marine isotope stage (MIS) 5e sea level high stand.Assuming global sea level during MIS 5e was ca. 4–5 m above present-day sea level (McCulloch and Esat, 2000) and the growth position of the corals was 1–5 m below sea level, the terraces have been uplifted between 12 and 25 m (12–15 cm/kyr). This is consistent with other terrace-based uplift rates for the central Baja California peninsula, north of the La Paz fault.  相似文献   

Loss on ignition: a qualitative or quantitative method for organic matter and carbonate mineral content in sediments?   总被引：5，自引：7，他引：5  

Juan I. Santisteban  Rosa Mediavilla  Enrique López-Pamo  Cristino J. Dabrio  M. Blanca Ruiz Zapata  M. José Gil García  Silvino Castaño  Pedro E. Martínez-Alfaro 《Journal of Paleolimnology》2004,32(3):287-299

Since the publication of the paper of , loss on ignition (LOI) has been widely used as a method to estimate the amount of organic matter and carbonate mineral content (and indirectly of organic and inorganic carbon) in sediments. The relationships between LOI at 550 °C (LOI₅₅₀) and organic carbon (OC) content and between LOI at 950 °C (LOI₉₅₀) and inorganic carbon (IC) content are currently accepted as a standard. However, the comparison of 150 analyses of samples of diverse lithologies, collected from a single core, reveals that these relationships are affected by sediment composition (presence of clays, salts, and the variable content of organic carbon). This results in an incremental error on the estimation of carbon content from LOI values that invalidates the use of LOI values as a quantitative method for estimating carbon content. Conversely, the general trends of LOI₅₅₀ and LOI₉₅₀ show a good correlation with carbon content (both organic and inorganic) allowing use of LOI as a qualitative test for carbon content. Similarly, in our case, LOI at 105 °C (LOI₁₀₅) is a good qualitative proxy for the trends in gypsum content.  相似文献   

Seismic base‐isolation by use of a telescoping stepping mechanism     

Maria D. Martinez‐Rodrigo  J. Enrique Luco 《地震工程与结构动力学》2005,34(3):227-245

A new base‐isolation mechanism corresponding to a variance of the stepping A‐shaped frame is proposed and its seismic performance is investigated numerically for strong ground accelerations with peak values in the range from 0.5 to 1g. In its simplest two‐dimensional form, the system consists of a frame with two telescoping legs pinned at the apex at a sharp angle. The legs are attached to the foundation through a spring and a damper acting in parallel. Both the springs and viscous dampers have bilinear characteristics that make them very stiff in compression but very soft in tension. As the structure rocks sideways, the length of the loaded leg remains essentially constant while the length of the unloaded leg increases. When the ground acceleration changes direction, the process is reversed. The resulting system has three main characteristics: (i) as the structure steps on a rigid leg, the maximum acceleration that can be transmitted to the superstructure is limited to a value which is approximately independent of the amplitude of the ground motion; (ii) there is a systematic lifting of the superstructure with kinetic energy being systematically transformed into potential energy during the strong phase of the ground motion; and (iii) the system is slowly self‐centering at the end of the earthquake. The seismic performance of the system is evaluated for a tall bridge pier and for a smaller frame that could be used in a multi‐story building. The results obtained for the 1940 El Centro ground motion scaled to 1g and for the near‐field Rinaldi ground motion recorded during the Northridge earthquake show that substantial reductions of the absolute acceleration can be obtained with reasonable relative displacements of the superstructure and small strokes in the isolation devices. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

The Aguablanca Ni–(Cu) sulfide deposit, SW Spain: geologic and geochemical controls and the relationship with a midcrustal layered mafic complex     

Fernando Tornos  Carmen Galindo  César Casquet  Luis Rodríguez Pevida  César Martínez  Enrique Martínez  Francisco Velasco  Alexander Iriondo 《Mineralium Deposita》2006,41(8):737-769

The Aguablanca Ni–(Cu) sulfide deposit is hosted by a breccia pipe within a gabbro–diorite pluton. The deposit probably formed due to the disruption of a partially crystallized layered mafic complex at about 12–19 km depth and the subsequent emplacement of melts and breccias at shallow levels (<2 km). The ore-hosting breccias are interpreted as fragments of an ultramafic cumulate, which were transported to the near surface along with a molten sulfide melt. Phlogopite Ar–Ar ages are 341–332 Ma in the breccia pipe, and 338–334 Ma in the layered mafic complex, and are similar to recently reported U–Pb ages of the host Aguablanca Stock and other nearby calc-alkaline metaluminous intrusions (ca. 350–330 Ma). Ore deposition resulted from the combination of two critical factors, the emplacement of a layered mafic complex deep in the continental crust and the development of small dilational structures along transcrustal strike-slip faults that triggered the forceful intrusion of magmas to shallow levels. The emplacement of basaltic magmas in the lower middle crust was accompanied by major interaction with the host rocks, immiscibility of a sulfide melt, and the formation of a magma chamber with ultramafic cumulates and sulfide melt at the bottom and a vertically zoned mafic to intermediate magmas above. Dismembered bodies of mafic/ultramafic rocks thought to be parts of the complex crop out about 50 km southwest of the deposit in a tectonically uplifted block (Cortegana Igneous Complex, Aracena Massif). Reactivation of Variscan structures that merged at the depth of the mafic complex led to sequential extraction of melts, cumulates, and sulfide magma. Lithogeochemistry and Sr and Nd isotope data of the Aguablanca Stock reflect the mixing from two distinct reservoirs, i.e., an evolved siliciclastic middle-upper continental crust and a primitive tholeiitic melt. Crustal contamination in the deep magma chamber was so intense that orthopyroxene replaced olivine as the main mineral phase controlling the early fractional crystallization of the melt. Geochemical evidence includes enrichment in SiO₂ and incompatible elements, and Sr and Nd isotope compositions (⁸⁷Sr/⁸⁶Sr_i 0.708–0.710; ¹⁴³Nd/¹⁴⁴Nd_i 0.512–0.513). However, rocks of the Cortegana Igneous Complex have low initial ⁸⁷Sr/⁸⁶Sr and high initial ¹⁴³Nd/¹⁴⁴Nd values suggesting contamination by lower crustal rocks. Comparison of the geochemical and geological features of igneous rocks in the Aguablanca deposit and the Cortegana Igneous Complex indicates that, although probably part of the same magmatic system, they are rather different and the rocks of the Cortegana Igneous Complex were not the direct source of the Aguablanca deposit. Crust–magma interaction was a complex process, and the generation of orebodies was controlled by local but highly variable factors. The model for the formation of the Aguablanca deposit presented in this study implies that dense sulfide melts can effectively travel long distances through the continental crust and that dilational zones within compressional belts can effectively focus such melt transport into shallow environments.Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.  相似文献   

Discussion of the paper “soil-structure interaction in coupled rocking and sliding vibration—the plane problem”     

J. Enrique Luco 《Soil Dynamics and Earthquake Engineering》1986,5(4):253-254

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On the relation between radiation and scattering problems for foundations embedded in an elastic half-space     

J. Enrique Luco 《Soil Dynamics and Earthquake Engineering》1986,5(2)

The relation between the solutions of the boundary-value problems for the dynamic response of embedded foundations to external forces and seismic excitation is examined. It is shown that the contact tractions obtained in the course of calculating the response to external forces can also be used to determine the response of the foundation to an arbitrary seismic excitation.  相似文献